Dipartimento di Fisica - Tesi di Dottorato

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Llow dimensional materials synthesis, characterization and applications
(2017-02-24) Coello Fiallos, Diana Carolina; Pantano, Pietro; Caputi, Lorenzo; Tavolaro, Adalgisa
This thesis was carried out at the laboratory of the Surface Nanoscience in the Department of Physics of University of Calabria, and at the Institute of Membrane Technology (ITM) of CNR, dealing the study of nanostructured systems with low dimensionality. The first part of the work consisted in the synthesis and characterization of graphite oxide (GO), obtained by chemical oxidation and sonication of natural graphite. We used an innovative oxidation process with respect to those present in the literature, and the resulting material was studied by means of UV-visible and Infrared absorption spectroscopy, Raman and XPS spectroscopies, and by TEM and SEM microscopies. The sonicated graphite oxide (sGO) was tested for adsorption of dyes, with the aim to contribute to research in the field of the reduction of pollutants in the liquid phase. We used Methylene Blue, Acridine Orange and Cresyl Violet dyes, whose kinetics of adsorption on sGO was been meticulously studied by the UV-visible absorption spectroscopy. The results showed that the graphite oxide effectively absorbs the three dyes, and the chemical nature of the adsorption process was evidenced by means the kinetic simulations adopting different models. The second part of the work relates to the synthesis of carbon-based nanostructures of the type "nano-onions" (CNOs), similar to multi-layer fullerenes, of great scientific and technological interest. The CNOs can be obtained by means of arc discharge between carbon electrodes immersed in deionized water. This method was used in this thesis work, and the produced carbonaceous nanomaterials have been characterized by Raman spectroscopy and TEM microscopy. Particular attention has been paid to those nanomaterials that contain a high percentage of CNO, since the arc discharge method also generates carbon nanotubes (CNT) and amorphous carbon. The main finding of the research was the identification of a solid agglomerate on the cathode, consisting almost exclusively of polyhedral CNOs and turbostratic graphite. The genesis of such CNOs is not attributable to a crystallization process of the carbon ions expelled from the plasma zone towards the surrounding water. The evidence of the fact that during the discharge the cathode remains at a temperature certainly lower respect to the anode, has permitted to hypothesize the CNOs training process, in which the carbon ions crystallize in the presence of a temperature gradient in the immediate vicinity of the cathode surface. In the last part of this research activity, I investigated a crystal of Indium Selenium (InSe) by means of different electron spectroscopies, in ultra-high vacuum conditions. Through electron energy loss spectroscopy (EELS) the electronic properties of InSe and its reactivity towards oxygen and air have been studied. The results have allowed to identify the most relevant transitions between electronic states in good agreement with existing theoretical calculations of the electronic structure and density of states. Experimental observations have also shown that the material is very stable with respect to possible oxidizing agents.
Sorveglianza fisica della protezione contro Ie radiazioni ionizzanti relativa alia costruzione e all'esercizio della sorgente STAR nell'ambito del progetto materia
(2014-11-28) Martire, Fiorello; Bartolino, Roberto; Agostino, Raffaele
Proprietà elettroniche collettive del grafene supportato: influenza del substrato
(2014-11-12) Ligato, Nadia; Pantano, Pietro; Caputi, Lorenzo; Cupolillo, Anna
Dielectric characterization of different mesogenic substances and a mixture with non-conventional gold nanoparticles
(2012-11-28) Marino, Lucia; Versace, Carlo; Bertolini, Roberto; Scaramuzza, Nicola
The study of liquid-crystalline matter and nano-structured materials is an important and vast field of research with potential implications in the development of new technologies, like sensors and displays. In this work we have analyzed and characterized different systems by dielectric spectroscopy. The first part of this thesis is devoted to the characterization of an orthoconic liquid-crystalline mixture, W-129, with ferroelectric properties. The analysis of the dielectric response of this material has revealed a plurality of ferroelectric smectic C* subphases; they represent smectic intermediate variants situated between the ferroelectric phase and the antiferroelettric one, known like antiferrielectric phases (SmCFI*, SmCFII*, ... ), whose study is still open and is collecting a lot of interest in academic environments. The same liquid crystalline mixture was then doped with unconventional gold nanoparticles. These nanoparticles are functionalized with a hydrophilic polymer which becomes hydrophobic exceeded 40°C. The nano-composite material obtained by the dispersion of the gold nanoparticles presents interesting characteristics, such as an enhancement of dielectric increments (or strengths) probably due to the molecular interactions between the ferroelectric liquid crystal and the gold nanoparticles, which translates into an increase of the order of the liquid crystal host, in a stabilization of the smectic subphases and in an enhanced memory effect already seen in the pure liquid-crystalline mixture. The third and last part is devoted to the characterization of a new "banana-shaped" liquid crystal, which exhibits some unusual physical properties during the nematic phase, in particular, the presence of regions of more ordered molecules, organized in a smectic C phase inside a nematic one. The dielectric spectra acquired during the nematic phase show the presence of a relaxation response between 10 and 20 Hz which, with the addition of relatively large values of permittivity, may suggest the presence of a ferroelectric response due to the existence of cybotactic clusters.
Measurement of the top quark pair differential cross sections with the atlas detector at the LHC
(2012-12-03) Lavorini, Lavorini; Tassi, Enrico; Fiore, Roberto
Electronic and vibrational properties of ultrathin layers adsorbed on metal surfaces
(2011) Marino, Antonio Raimondo; Chiarello, Gennaro; Carbone, Vincenzo; Bartolino, Roberto
Periodic Structures in Composite Materials for Photonics Applications
(2014-06-16) De Sio, Luciano; Umeton, C.; Longeri, M.
Theoretical study of ion induced electronic processes at metal surface
(2014-05-19) Rudi, Sarah Anna; Sindona, Antonio; Falcone, Giovanni

Dipartimento di Fisica - Tesi di Dottorato

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