OpenAire - Articoli F7P

Permanent URI for this collectionhttp://localhost:4000/handle/10955/441

In questa collezione speciale sono raggruppati i lavori pubblicati con i finanziamenti europei relativi al 7° Programma Quadro (in accordo alla clausola 39). --- Special collection to bring together all research outputs from EU and ERC funded projects. Research outputs remain in the subject collections but are also copied here to meet the requirements of EU OpenAIRE harvesting.

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    Probing membrane and interface properties inconcentrated electrolyte solutions
    (2014-04-14) Fontananova, Enrica; Zhang,Wenjuan; Nicotera, Isabella; Simari,Cataldo; van Baak,Willem; Di Profio,Gianluca; Curcio,Efrem; Drioli, Enrico
    This study deals with the membrane and interface electrical properties investigation by electrochemical impedance spectroscopy (EIS). The EIS is a powerful technique for characterizing electrical behavior of systems in which coupled electrical processes occur at different rates.A systematics tudy on the effect of solution concentration,temperature and velocity, on the electrical resistance of anion-and cation- exchange membranes (AEMs and CEMs) and their interfaces (electrical double layer and diffusion boundary layer), was carried out. At the best of our knowledge, for t he first time electrolyte concentrations up to 4 M were used for the study of membranes and interface by EIS. Moreover, Pulsed Gradient Spin Echo Nuclear Magnetic Resonance (PGSE-NMR)technique was used to measure the water self-diffusion coefficients in swelled membrane as a function of the solution concentration and temperature.These measurements gave additional important insights about the effect of the electrolyte solution and fixed charges concentration in membrane,on membrane microstructure and its transport and electrical properties. & 2014TheAuthors.PublishedbyElsevierB.V.ThisisanopenaccessarticleundertheCCBY
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    Light scattering methods to test inorganic PCMs for application in buildings
    (IOP, 2017) De Paola, Maria Gabriela; Calabrò, Vincenza; De Simone, Marilena
    Thermal performance and stability over time are key parameters for the characterization and application of PCMs in the building sector. Generally, inorganic PCMs are dispersions of hydrated salts and additives in water that counteract phase segregation phenomena and subcooling. Traditional methods or in “house” methods can be used for evaluating thermal properties, while stability can be estimated over time by using optical techniques. By considering this double approach, in this work thermal and structural analyses of Glauber salt based composite PCMs are conducted by means of non-conventional equipment: T-history method (thermal analysis) and Turbiscan (stability analysis). Three samples with the same composition (Glauber salt with additives) were prepared by using different sonication times and their thermal performances were compared by testing both the thermal cycling and the thermal properties. The stability of the mixtures was verified by the identification of destabilization phenomena, the evaluation of the migration velocities of particles and the estimation of variation of particle size.
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    Thermal and Stability Investigation of Phase Change Material Dispersions for Thermal Energy Storage by T-History and Optical Methods
    (MDPI, 2017-03) De Paola, Maria Gabriela; Arcuri, Natale; Calabrò, Vincenza; De Simone, Marilena De Simone
    Glauber’s salt (sodium sulphate decahydrate) is a promising phase change material (PCM) for use in the building sector, thanks to its high enthalpy of fusion associated with a proper phase transition temperature. It also offers economic and environmental advantages because it can be obtained as a byproduct from the disposal process of lead batteries. However, due to phenomena of phase segregation and supercooling, Glauber’s salt cannot be used in its pure state and requires the addition of rheological modifiers and nucleating agents. In this work, the initial thermal performances of mixtures based on Glauber’s salt with different compositions are compared by using the T-history method and adopting sonication for mixing, and following the same preparation procedure for all the samples. With fixed composition, the effects of the addition sequence of the reagents are also examined. The analysis carried out by optical methods based on light scattering (Turbiscan equipment) allowed us to identify the kinetics of destabilization for each sample and revealed the need to specify in detail the preparation stages of PCMs, in order to make the composition reproducible in the laboratory and on a wider scale